Tuesday, June 7, 2011

RANCIDITY

 When fats and oils are oxidised, they become rancid and their smell and taste change. Usually substances which prevent oxidation (antioxidants) are added to foods containing fats and oil. Keeping food in air tight containers helps to slow down oxidation. Do you know that chips manufacturers usually flush bags of chips with gas such as nitrogen to prevent the chips from getting oxidised ?

 The non-metals are either solids or gases except bromine which is a liquid.

 Aqua regia, (Latin for ‘royal water’) is a freshly prepared mixture of concentrated hydrochloric acid and concentrated nitric acid in the ratio of 3:1. It can dissolve gold, even though neither of these acids can do so alone. Aqua regia is a highly corrosive, fuming liquid. It is one of the few reagents that is able to dissolve gold and platinum.

 Pure gold, known as 24 carat gold, is very soft. It is, therefore, not suitable for making jewellery. It is alloyed with either silver or copper to make it hard. Generally, in India, 22 carat gold is used for making ornaments. It means that 22 parts of pure gold is alloyed with 2 parts of either copper or silver.

 Allotropes of carbon:The element carbon occurs in different forms in nature with widely varying physical properties. Both diamond and graphite are formed by carbon atoms, the difference lies in the manner in which the carbon atoms are bonded to one another. In diamond, each carbon atom is bonded to four other carbon atoms forming a rigid three-dimensional structure. In graphite, each carbon atom is bonded to three other carbon atoms in the same plane giving a hexagonal array. One of these bonds is a double-bond, and thus the valency of carbon is satisfied. Graphite structure is formed by the hexagonal arrays being placed in layers one above the other. These two different structures result in diamond and graphite having very different physical properties even though their chemical properties are the same. Diamond is the hardest substance known while graphite is smooth and slippery. Graphite is also a very good conductor of electricity unlike other non-metals. Diamonds can be synthesised by subjecting pure carbon to very high pressure and temperature. These synthetic diamonds are small but are otherwise indistinguishable from natural diamonds. Fullerenes form another class of carbon allotropes. The first one to be identified was C-60 which has carbon atoms arranged in the shape of a football. Since this looked like the geodesic dome designed by the US architect Buckminster Fuller, the molecule was named fullerene.

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